Product ID:LACQUER OLIVE DRAB 34088
MSDS Date:08/05/1992
FSC:8010
NIIN:00-190-3360
MSDS Number: BRFMH

CRAWFORD LABS, INC

4165 S EMERALD AVE
CHICAGO, IL 60609
US

Emergency Phone: 312-433-1307

Info Phone: 312-376-7132

Preparer: DAVID SCHMETTERER

Cage: 5V430

CRAWFORD LABORATORIES, INC

CHICAGO, IL 60609 US

Telephone: 312-376-7132

Cage: 5V430

TOLUENE (SARA 313) (VAPOR PRESSURE 38 MM HG) (CONTAINS A

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 20-50%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ISOPROPYL ALCOHOL (SARA 313) (VAPOR PRESSURE 33 MM HG)

CAS: 67-63-0

RTECS: NT8050000

Fraction By Weight: 5-20%

OSHA PEL 400 PPM/500 STEL

ACGIH TLV: 400 PPM/500 STEL

ISOBUTYL ISOBUTYRATE (VAPOR PRESSURE 3.2 MM HG)

CAS: 97-85-8

RTECS: NQ5250000

Fraction By Weight: 5-20%

METHYL ETHYL KETONE (SARA 313) (VAPOR PRESSURE 71.2 MM HG)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 1-5%

OSHA PEL 100 PPM

ACGIH TLV: 200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHYL ISOBUTYL KETONE (SARA 313) (VAPOR PRESSURE 15 MM

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 5-20%

OSHA PEL 100 PPM/75 STEL

ACGIH TLV: 50 PPM/75 STEL; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

NORMAL BUTYL ALCOHOL (SARA 313) (VAPOR PRESSURE 4.8 MM HG)

CAS: 71-36-3

RTECS: EO1400000

Fraction By Weight: 5-20%

OSHA PEL 100 PPM

ACGIH TLV: S, C 50 PPM; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LEAD (SARA 313) (WARNING-DRIED FILM OF THIS PAINT MAY BE

CAS: 7439-92-1

RTECS: OF7525000

Fraction By Weight: 1-5%

OSHA PEL 0.05 MG/M3

ACGIH TLV: .15 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

CHROMATE (AS CR+6)

CAS: 1333-82-0

RTECS: GB6650000

Fraction By Weight: 1-5%

OSHA PEL .1 MG/M3

ACGIH TLV: .05 MG/M3

CRYSTALLINE SILICA

CAS: 14464-46-1

RTECS: VV7325000

Fraction By Weight: 5-20%

OSHA PEL SEE TABLE Z3

ACGIH TLV: 0.05 MG/M3 RDUST9293

MAGNESIUM SILICATE HYDRATE

CAS: 14807-96-6

RTECS: MW2700000

Fraction By Weight: 1-5%

ACGIH TLV: 2 MG/M3

DIOCTYL PHTHALATE (SARA 313) (VAPOR PRESSURE 1.2 MM HG)

CAS: 117-81-7

RTECS: TI0350000

Fraction By Weight: 1-5%

ACGIH TLV: 5 MG/M3

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

NITROCELLULOSE

CAS: 9004-70-0

RTECS: WG2934500

Fraction By Weight: 1-5%

OSHA PEL NONE ESTABLISHED

ACGIH TLV: NONE ESTABLISHED

TALC (ALSO CONTAINS LESS THAN 5% OF DOLOMITE, CHLORITE,

CAS: 14807-96-6

RTECS: MW2700000

Fraction By Weight: 1-5%

VOC 617 G/L

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE TOXICITY, RESULTING IN HEADACHE,
DIZZINESS, NAUSEA AND LOSS OF CONSCIOUSNESS. SEVERE EYE IRRITATION
POSSIBLY RESULTING IN PERMANENT DAMAGE. IRRITATED MUCOUS MEMBRANES.
VOMITING DUE TO INGESTION. DEFATTING AND DRYING OF THE SKIN.
SENSITIZATION AFTER REPEATED CONTACT. IF INGESTED, LIQUID OR MIST
MAY CAUSE MODERATE*
Explanation of Carcinogenicity:CRYSTALLINE SILICA & MAGNESIUM SILICATE
HYDRATE ARE LISTED BY IARC ALONG W/DIOCTYL PHTHALATE AS POTENTIAL
CARCINOGENICS
Effects of Overexposure:*GASTRIC AND SYSTEMIC UPSET, INCLUDING NAUSEA
AND ABDOMINAL CRAMPS

First Aid:EYE: FLUSH W/LUKEWARM LOW PRESS WTR 15 MINS, LIFT LIDS. GET
MED AID. INHAL: REMOVE TO FRESH AIR-GIVE OXYGEN IF BREATH DIFF &
ARTIF RESP IF NOT BREATH. GET MED AID. KEEP WARM/COMFY NEVER GIVE
UNCONSCIO US PERSON LIQ. INGEST: CALL DR IMMED. INDUCE VOMIT BY DR
INSTRUCT ONLY. IF VOMIT OCCURS SPONTANEOUSLY-KEEP HEAD BELOW HIPS
TO PREVENT ASPIR OF LIQ INTO LUNGS. NOTHING BY MOUTH TO UNCONSCIOUS
PERSON

Flash Point Method:SCC
Flash Point:25.0F,-3.9C
Lower Limits:0.28
Extinguishing Media:FOAM, CO2, OR DRY CHEMICAL
Fire Fighting Procedures:MAY USE WTR TO KEEP EXPOSED CNTNRS
COOL/FLAMMABLE STRUCTURES WET. DO NOT ENTER FIRE AREA WITHOUT
PROPER PROTECTION AS HAZARDOUS DECOMP PRODUCTS MAY BE PRESENT
Unusual Fire/Explosion Hazard:WATER PRESSURE MAY SPREAD A FLAMMABLE
LIQUID FIRE. SEALED CONTAINERS MAY EXPLODE IF OVERHEATED.

Spill Release Procedures:WARNING-FLAMMABLE. ELIMINATE ALL IGNITION
SOURCES. HANDLING EQUIPMENT MUST BE FOUNDED TO PREVENT SPARKING.
SOAK UP WITH AN ABSORBENT AND PLACE IN NON-LEAKING CONTAINERS. SEAL
TIGHTLY FOR PROPER DISPOS AL.
Neutralizing Agent:N/K FLUSH WITH WATER WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES. FOLLOW

Handling and Storage Precautions:TREAT AS HAZ-FLAMM MATL. KNOW APPLIC
D.O.T REG BEFORE ATTEMPT TRANSPORT OF MATL. "WARNING: HOT ORGANIC
CHEM VAPORS/MIST ARE SUSCEPTIBLE TO SUDDEN#
Other Precautions:#SPONTANEOUS COMBUST WHEN MIXED W/AIR. IGNIT MAY
OCCUR AT TEMP BELOW THOSE PUBLISHED IN THE LITERATURE AS
"AUTOIGNITION"/"IGNITION" TEMP. IGNIT TEMP DECREASE W/INCREAS VAPOR
VOL & VAPOR/AIR CONTACT TI ME & ARE INFLUENCED BY PRESS CHANGES.##

Respiratory Protection:IMPORTANT-MUST PROVIDE ADEQUATE VENTILATION TO
MAINTAIN VAPOR CONCENTRATIONS BELOW THE ESTABLISHED TLV LIMIT AS
GIVEN BY OSHA. IN MORE CONFINED AREAS A NIOSH-MSHA APPROVED
RESPIRATOR EQUIPPED WITH ORG ANIC VAPOR CARTRIDGE SHOULD BE WORN.
Ventilation:MUST PROVIDE ADEQ VENT. ##IGNIT MAY OCCUR AT TYPICAL
ELEVATED TEMP PROCESS CONDTN, ESP IN PROCESS OPERATING UNDER+
Protective Gloves:RUBBER
Eye Protection:APPROVED SAFETY GOGGLES/FACE SHIELDS
Other Protective Equipment:HAVE EYE BATH AND SAFETY SHOWER AVAILABLE.
Work Hygienic Practices:N/K +VACUUM IF SUBJECTED TO SUDDEN INGRESS
OF AIR OR OUTSIDE PROCESS EQUIP OPERATING UNDER ELEVATED PRESSURE
IF++
Supplemental Safety and Health
++SUDDEN ESCAPE OF VAPORS OR MISTS TO THE ATMOSPHERE OCCURS. ANY
PROPOSED USE OF THIS PRODUCT IN ELEVATED TEMPERATURE PROCESSES
SHOULD BE THOROUGHLY EVALUATED TO ASSURE THAT SAFE OPERATING
CONDITIONS ARE ESTABLISHED AND MAINTAINED

HCC:F2
Boiling Pt:B.P. Text:174-446F
Vapor Density:> THAN AIR
Spec Gravity:1.12
Evaporation Rate & Reference:1.36 X N-BUTYL ACETATE
Solubility in Water:SLIGHT
Appearance and Odor:GREEN LIQUID
Percent Volatiles by Volume:73.2%
Corrosion Rate:NONCORR

Stability Indicator/Materials to Avoid:YES
MAY BE INCOMPATIBLE WITH OXIDIZING AGENTS AND STRONG ALKALIES
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES &
INCOMPATIBILITES SUCH AS OXIDIZING AGENTS AND STRONG ALKALIES
Hazardous Decomposition Products:INCOMPLETE COMBUSTION FOR PRODUCTS
LIKE THIS MAY GENERATE HIGHLY POISONOUS CARBON MONOXIDE AND OTHER
TOXIC GASES

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH CURRENT
LOCAL, STATE AND FEDERAL REGULATION. CONTACT AN APPROVED DISPOSAL
FACILITY. BY WASHING WITH SOAP AND WATER. DO NOT REUSE
CONTAMINATED CLOTHING OR SHO ES. IF IRRITATION PERSISTS, GET
MEDICALATTENTION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.